Anarapid gel drying solution - anamed Elektrophorese Gele und ...

Safety Safety data data sheet sheet in in accordance accordance with with Regulation Regulation (EC) (EC) No No 1907/2006 

1907/2006 

Revision: Revision: 30 30.04.201 30 .201 .2011 .201 

Version: Version: 00 0011 00 11 

Replacement of version 00 0010 00 

of 29 29.01.20 29 .20 .2010 .20 

1. 1. Identification Identification of of the the substance/mixture substance/mixture and and of of the the company/undertaking 

company/undertaking 

1.1 1.1 Product Product Product Product identifier identifier identifier identifier 

Trade name AnaRapid AnaRapid Geldrying Geldrying solution 

solution 

Product number anam0017 

Item code AR10/03 

Formulation Anarapid 

Formulation number 11/05 

1.2 1.2 1.2 Relevant Relevant Relevant Relevant identified identified identified identified uses uses uses uses of of of of the the the the substance substance substance substance or or or or mixture mixture mixture mixture and and and and uses uses uses uses advised advised advised advised against against against against 

The product is used for electrophoresis in analytical laboratories. 

1.3 1.3 1.3 Details Details Details Details of of of of the the the the supplier supplier supplier supplier of of of of the the the the safety safety safety safety ddata 

dd 

ata ata ata sheet sheet sheet sheet 

anamed Elektrophorese GmbH 

Ringstraße 4 

D-64401 Gross-Bieberau 

Telephone: int+49-(0)6162-809840 

e-mail-address of the competent person responsible for this Safety Data Sheet: 

urban-finking.gefstoff@t-online.de 

Technical contact: 

anamed Elektrophorese GmbH 

Frau Dr. Vera Kreis / Herr Dieter Lindenberger 

Telephone int+49-(0)6162-809840 

Fax int+49-(0)6162-8098420 

1.4 1.4 1.4 Emergency Emergency Emergency Emergency telephon telephone telephon telephone 

e e number number number number 

Poison Control Center Mainz (Giftinformationszentrum Mainz) or local poison centers 

Telephone int+49-(0)6131 19 2 40 

2. 2. 2. Hazards Hazards identification 

identification 

2.1 2.1 Classification Classification Classification Classification of of of of the the the the substance substance substance substance or or or or mixture mixture mixture mixture 

R10 

The product is flammable within the meaning of the current version of Directive 1999/45/EC. 

2.2 2.2 Label Label Label Label elements elements elements elements 

Symbol(s) of danger: Not required. 

Indication(s) of danger: Not required. 

Hazardous component(s) to be indicated on label: Not required. 

R phrases: R10 Flammable 

S phrases: S7 Keep container tightly closed. 

S16 Keep away from sources of ignition – No smoking. 

Special labelling for certain mixtures: None. 

Remarks: None. 

2.3 2.3 Other Other Other Other hazards hazards hazards hazards 

Prolonged or repeated skin contact may cause removal of natural fat from the skin resulting in dermatitis 

(skin inflammation). 

The product is a flammable liquid. Vapours can form explosive mixtures with air even at normal temperatures. 

The product is classified as low hazardous to water. 

The mixture does not meet the criteria for PBT or vPvB. 

Page 1 of 9

Safety Safety data data sheet sheet in in accordance accordance accordance with with Regulation Regulation (EC) (EC) No No 1907/200 1907/2006 1907/200 

Page 2 of 9 

Trade name: AnaRapid Geldrying solution 

Company/Undertaking: anamed Elektrophorese Elektrophorese GmbH 

Ringstraße Ringstraße 44, 

4 , DD-64 

D 64 6440 

401 40 1 Gross Gross-Bieber 

Gross 

Bieber Bieberau Bieber au 

Telephone: int+49 int+49-(0)61 

int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 

Product number: anam0017 

3. Composition/inform 

Composition/information Composition/inform ation on ingredients 

3.2 Mixtures Mixtures Mixtures Mixtures 

3.2.1 Characterisation 

Characterisation 



This product is a mixture. It is a combination of special active substances in aqueous alcoholic solution. 

3.2.2 Substances Substances Substances Substances presenting presenting presenting presenting a a a a health/environmental health/environmental health/environmental health/environmental hazard hazard hazard hazard within within within within the the the the meaning meaning meaning meaning of of of of Directive Directive Directive Directive 67/548/ 67/548/EEC 

67/548/ 67/548/ EEC EEC EEC 

CAS No EC EC No No 

Identification % by weight weight Classification Classification Indication(s) 

of of of danger danger 

danger 

64-17-5 200-837-3 ethanol < 30 F; R11 Highly flammable 

See See subsection subsection 2.2 2.2 for for further further details details. details . Full text of of the R phrases see subsection 16.2. 

16.2. 

3.2.3 Substances Substances Substances Substances presenting presenting presenting presenting a aa 

a health/environmental health/environmental health/environmental health/environmental hazard hazard hazard hazard within within within within the the the the meaning meaning meaning meaning of of of of Regulation Regulation Regulation Regulation (EC) (EC) (EC) (EC) No No No No 1272/2008 

1272/2008 

1272/2008 

1272/2008 

CAS No EC EC No No 

Identification % by weight weight Classification 

Classification 

64-17-5 200-837-3 ethanol < 30 Flam. Liq. 2; H225 

3.2.4 See See number number 16.4.2 16.4.2 for for further further further details. details. Full Full text text of of the hazard sta statements sta 

tements see subsection 16. 16.3. 16. 

Substances Substances Substances 

Substances which which which which are are are are assigned assigned assigned assigned Community Community Community Community workplace workplace workplace workplace exposure exposure exposure exposure limits limits limits limits and and and and which which which which are are are are not not not not already already already already included included included included under under under under 

points points points points 3333.2.2 .2.2 .2.2 .2.2 and and and and 3.2.3 3.2.3 3.2.3 3.2.3 (see (see (see (see also also also also SSSSection ection ection ection 8.) 8.) 8.) 8.) 

No substances. 

3.3 Additional Additional Additional Additional information 

information 

information 

information 

The product contains < 10% polyethylene glycol 200. 

National occupational exposure limit values for various member states of the EU have been specified. 

4. First First aid aid measures 

measures 

4.1 Description Description Description Description of of of of first first first first aid aid aid aid measures measures measures measures 

4.1.1 General General General General information 

information 

information 

information 

Remove contaminated, soaked clothing immediately and wash before reuse. 

Emergency eyewash should be provided in the immediate working surroundings. 

4. 4.1. 4. 

1. 1.2 1. In In In In case case case case of of of of inhalation inhalation inhalation inhalation 

Remove the casualty into fresh air. In case of breathing difficulties administer oxygen. 

By continuous complaints seek medical advice. 

4. 4.1. 4. 

1. 1.3 1. In In In In case case case case of of of of contact contact contact contact with with with with skin skin skin skin 

In case of contact with skin, wash off immediately with water. Consult a doctor if skin irritation persists. 

4. 4.1. 4. 

1. 1.4 1. In In In In case case case case of of of of contact contact contact contact with with with with eyes eyes eyes eyes 

In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids 

apart and seek medical advice. Remove contact lenses, if present and easy to do. 

4. 4.1. 4. 

1. 1.5 1. In In In In case case case case of of of of ingestion ingestion ingestion ingestion 

Rinse mouth thoroughly with water and spit out liquid immediately. 

Let water be swallowed in little sips (dilution effect). 

Seek medical advice. 

4.2 Most Most Most Most important important important important symptoms symptoms symptoms symptoms and and and and effects, effects, effects, effects, both both both both acute acute acute acute and and and and delayed delayed delayed delayed 

Headache, dizziness, inebriation, nausea, heartburn, vomiting, excitation, narcotic effect, removal of natural fat from 

the skin resulting in dermatitis. 

4.3 Indication Indication Indication Indication of of of of any any any any immediate immediate immediate immediate medical medical medical medical attention attention attention attention and and and and special special special special treatment treatment treatment treatment needed needed needed needed 

No information available. 

5. 5. Firefighting Firefighting measures 

measures 

5.1 5.1 EEEExtinguishing xtinguishing xtinguishing xtinguishing media media media media 

5.1.1 5.1.1 Suitable Suitable Suitable Suitable extinguishing extinguishing extinguishing extinguishing media media media media 

Water spray jet, carbon dioxide, dry powder, alcohol resistant foam. 

5. 5.1. 5. 1. 1.2 1. Unsuitable Unsuitable Unsuitable Unsuitable extinguishing ee 

extinguishing 

xtinguishing xtinguishing media media media media 

Full water jet. 

5. 5.2 5. Special Special Special Special hazards hazards hazards hazards arising arising arising arising from from from from the the the the substance substance substance substance or or or or mixture mixture mixture mixture 

In the event of fire the following can be released: carbon monoxide, carbon dioxide, formaldehyde. 

The vapours are heavier than air and can accumulate in high concentrations on the ground, in cavities, channels and 

cellars. Beware of reignition. 

Vapours can form explosive mixtures with air even at normal temperatures. 

5. 5.3 5. Advice Advice Advice Advice for for for for firefighters firefighters firefighters firefighters 

Wear self-contained breathing apparatus. 

Do not inhale explosion and combustion gases. 

Cool endangered containers with water spray jet out of sheltered position. Due to the high vapour pressure, containers 

are liable to burst if temperature rises. 

Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations. 

Use only explosion-proof equipment. Use only solvent-resistant equipment. 

Fire class in accordance with EN 2: B (fires of liquid or liquefying substances).


Page 3 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


6. 6. 6. Accidental release measures 

6.1 6.1 Personal Personal Personal Personal precautions,,,, precautions 

precautions 

precautions protective protective protective protective equipment equipment equipment equipment and and and and emergency emergency emergency emergency procedures 

procedures 

procedures 

procedures 

6.1.1 6.1.1 For For For For non----emergency non non non emergency emergency emergency personnel personnel personnel personnel 

Ensure adequate ventilation. Use personal protective clothing. Keep away sources of ignition. 

Do not inhale vapours/aerosols. Avoid contact with eyes and skin. 

Use respiratory protection if exposed to vapours. Keep away from unprotected people. 

6.1.2 6.1.2 For For For For emergency emergency emergency emergency responders responders responders responders 

For suitable fabric for personal protective clothing see Section 8. 

6.2 6.2 Environmental Environmental Environmental Environmental precautions 

preca preca precautions 

utions utions 

Do not discharge into the drains, the aquatic environment and soil. 

6.3 6.3 Methods Methods Methods Methods and and and and material material material material for for for for containment containment containment containment and and and and cleaning cleaning cleaning cleaning up up up up 

For large amounts: pump off product. 

For residues: pick up with non-combustible adsorbent (e.g. diatomaceous earth, expanded mica, sand) 

Dispose of absorbed material in accordance with the regulations. Send in suitable containers for recovery or disposal. 

Small amounts (up to 1 liter): flush away with plenty of water. 

6.4 6.4 Reference Reference Reference Reference to to to to other other other other sections sections sections sections 

For personal protective equipment see also Section 8. 

For disposal considerations see also Section 13. 

7. 7. Handling Handling and and storage 

storage 

7.1 7.1 7.1 Precautions Precautions Precautions Precautions for for for for safe safe safe safe handling hh 

handling 

andling andling 

7.1.1 7.1.1 7.1.1 Advice Advice Advice Advice on on on on safe safe safe safe handling handling handling handling 

Open and handle container with care. Avoid formation of vapours. 

Do not leave containers open. Use solvent-resistant equipment. 

Provide good room ventilation even at ground level (vapours are heavier than air). 

Avoid contact with eyes and skin. 

Comply with the minimum standards in accordance with TRGS 500. 1 

In designing the work process the model solutions of the protection guidelines 1001 , 1101 and 2001 must be taken 

into consideration. 

7.1.2 7.1.2 Advice Advice Advice Advice on on on on general general general general occupational occupational occupational occupational hygiene hygiene hygiene hygiene 

Do not inhale vapours/aerosols. Avoid contact with eyes and skin. 

Remove contaminated, soaked clothing immediately and wash before reuse. 

At work do not eat, drink, smoke or take drugs. 

Wash hands before breaks and after work. After cleaning apply high-fat content skin care cream. 

Set out skin protection guidelines. 

Emergency eyewash should be provided in the immediate working surroundings. 

7.2 7.2 Conditions Conditions Conditions Conditions for for for for safe safe safe safe storage, storage, storage, storage, including including including including any any any any incompatibilities 

incompatibilities 



7.2 7.2.1 7.2 .1 Advice Advice Advice Advice on on on on protection protection protection protection against against against against fire fire fire fire and and and and explosion explosion explosion explosion 

The German Operational Safety Regulation (Betriebssicherheitsverordnung) in accordance with EC-Directive 

1999/92/EC has to be observed. 

Keep away from sources of ignition. Do not smoke. Take precautionary measures against electrostatic loading. 

Only use explosion-proof equipment/fittings and anti-static equipped (spark-free) tools. 

Wear shoes with conductible soles. 

Vapours can form explosive mixtures with air even at normal temperatures. Beware of reignition. 

Ignitable mixtures can form in the empty container. 

7.2. 7.2.2 7.2. Requirements Requirements Requirements Requirements for for for for storage storage storage storage rooms rooms rooms rooms and and and and vessels vessels vessels vessels 

Keep only in original container. Keep container tightly closed. Keep in a cool, well-ventilated place. 

Provide solvent-resistant and impermeable floor or make sure that spills can be contained, e.g. in sump pallets or 

kerbed areas. 

7.2. 7.2.3 7.2. Advice Advice Advice Advice on on on on storage storage storage storage compatibility 

compatibility 

compatibility 

compatibility 

Do not store together with explosible and flammable material and oxidising agents. 

The information about joint storage given in Table 2 of TRGS 5101 must be observed. 

7.2. 7.2.4 7.2. Further Further Further Further information information information information on on on on storage storage storage storage conditions conditions conditions conditions 

Protect from sunlight. 

7.2. 7.2.5 7.2. Storage Storage Storage Storage class class class class (for (for (for (for Germany Germany Germany Germany only) only) only) only) 

LGK 3 (Flammable liquids) in accordance with TRGS 5101 . 

7.3 7.3 Specific Specific Specific Specific end end end end use(s) use(s) use(s) use(s) 

The product is only intended for the uses mentioned under subsection 1.2.


Page 4 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


8. 8. 8. Exposure Exposure controls/ controls/person 

controls/ erson ersonal erson al protection 

8.1 8.1 Control Control Control Control parameters 

parameters 

parameters 

parameters 

CAS number Identification Identification 

Limit values Remarks 

64-17-5 ethanol 1000 ml/m³ national limit value – eight hours 

for U.K. 

25322-68-3 polyethylene glycol 1000 mg/m³ national limit value – eight hours 

for Denmark and Slovakia 

1000 mg/m³ national limit value – eight hours 

(inhalable aerosol) 

for Austria and Germany 

2000 mg/m³ 

national limit value – 

short term for Denmark 

4000 mg/m³ 



short term for Austria 

8000 mg/m³ 


short term for Slovakia 

8000 mg/m³ 



short term for Germany 

Remark: There is no valid exposure limit value for polyethylene glycol existing in U.K. These values mentioned above 

should only be considered as an information and used as a clue with respect to a risk assessment in 

accordance with Directive 98/24/EC. 

8.2 8.2 Exposure Exposure Exposure Exposure controls controls controls controls 

8.2.1 8.2.1 Appropriate Appropriate Appropriate Appropriate engineering engineering engineering engineering controls controls controls controls 

See also subsection 7.1. 

Technical measures and appropriate working operations should be given priority over the use of personal protective 

equipment. 

The effectiveness of suitable protective measures must be controlled. Suitable assessment methods are described in the 

German TRGS 4021 . 

Preliminary measure of the concentration of ethanol with test tubes, e.g.: 

Compur (549 410 Typ: 104 S); Dräger (81 01 631 Typ: Alkohol 25/a); Auer (D5086818 Typ: Ethanol-100). 

Vapours can form explosive mixtures with air even at normal temperatures. The German Operational Safety Regulation 

(Betriebssicherheitsverordnung) in accordance with EC-Directive 1999/92/EC has to be observed. 

8.2.2 8.2.2 Individual Individual Individual Individual protection protection protection protection measures, measures, measures, measures, such such such such as as as as personal personal personal personal protective protective protective protective equipment equipment equipment equipment 

Personal protective equipment needs to be selected specifically for the workplace, depending on concentrations and 

quantities of the hazardous substances handled. In the cases of special applications, it is recommended to check the 

chemical resistance with the manufacturer/supplier of the personal protective equipment. 

8.2.2.1 8.2.2.1 Eye/face Eye/face Eye/face Eye/face protection protection protection protection 

Tightly fitting safety glasses in accordance with EN 166 (i.e. safety glasses with side shields). 

8.2.2.2 8.2.2.2 Skin Skin Skin Skin protection protection protection protection 

Hand protection protection: protection 

Protective gloves (solvent-resistant). 

Suitable: protective gloves of butyl rubber (0.5 mm; breakthrough time ≥ 8 h); 

protective gloves of fluorinated rubber (0.4 mm; breakthrough time ≥ 8 h); 

protective gloves of neoprene (0.5 mm; breakthrough time ≥ 2 h). 

Not suitable: protective gloves of natural rubber, nitrile rubber and PVC. 

Totally unsuitable: protective gloves of leather or textile. 

Wear cotton undermitten if possible. 

Under practical conditions, the maximum wearing period can be significantly lower. 

The protective gloves to be used must comply with the specifications of the standard EN 374. 

Body Body protection: 

protection: 

Solvent-resistant and antistatic protective clothing. 

8.2.2.3 8.2.2.3 Respiratory Respiratory Respiratory Respiratory protection protection protection protection 

In case of inadequate ventilation, and in case of formation of vapours/aerosols, wear respiratory protection. 

Suitable respiratory protection, e.g. full mask/half mask/filtering half mask with 

- gas filter, type A1 up to 1000ml/m³ (ppm); 

- gas filter, type A2 up to 5000ml/m³ (ppm); 

- gas filter, type A3 up to 10000ml/m³ (ppm). 

The limitations in wearing time according to the BGR 1902 (rule of the German employers´ liability insurance 

association) for the use of respirators have to observed. 

8.2.2.4 8.2.2.4 Thermal Thermal Thermal Thermal hazards hazards hazards hazards 

Not relevant. 

8.2.3 8.2.3 Environmental Environmental Environmental Environmental exposure exposure exposure exposure controls controls controls controls 

See Section 6.


Page 5 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


9. 9. 9. Physical Physical and and and chemical chemical properties 

properties 

9.1 9.1 IIIInformation 

nformation nformation 

nformation on on on on basic basic basic basic physical pp 

physical 

hysical hysical and and and and chemical chemical chemical chemical properties properties properties properties 

Physical state: liquid 

Colour: colourless 

Odour: alcoholic 

Odour threshold: no relevant 

pH (as supplied): not determined 

pH (of an aqueous solution): not determined 

Melting point/freezing point (°C): not determined 

Boiling point and boiling range (°C): not determined 

Flash point (°C), closed cup: 28 

Evaporation rate: no data available 

Flammability (solid, gas): not relevant 

Upper flammability or explosive limit (Vol-%): 27.7 (ethanol) (literature value) 3 

Lower flammability or explosive limit (Vol-%): 3.1 (ethanol) (literature value) 3 

Vapour pressure (20°C) (mbar): not determined 

Vapour density (20°C): not determined 

Density (g/cm³): not determined 

Solubility in water: miscible 

Soluble in: not determined 

Partition coefficient: n-octanol/water: - 0.30 (ethanol) (LOGKOW © databank) 4 

Auto-ignition temperature (°C): no data available 

Decomposition temperature (°C): no data available 

Viscosity: no data available 

Explosive properties: not explosive 

Oxidising properties: not relevant 

9.2 9.2 Other Other Other Other information 

information 

information 

information 

The product is not explosive however vapours can form explosive mixtures with air even at normal temperatures. 

10. 10. Stability Stability and reactivity 

10.1 10.1 Reactivity Reactivity Reactivity Reactivity 

Vapours can form explosive mixtures with air even at normal temperatures. 

10.2 10.2 Chemical Chemical Chemical Chemical stability stability stability stability 

The product is stable under normal ambient and anticipated storage and handling conditions of temperature 

and pressure. 

10.3 10.3 Possibility Possibility Possibility Possibility of of of of hazardous hazardous hazardous hazardous reactions reactions reactions reactions 

Strong exothermic reaction with strong oxidising agents, strong reducing agents, acids, acid anhydrides and 

alkali metals. 

Risk of explosion in case of uncontrolled reaction. 

10.4 10.4 Conditions Conditions Conditions Conditions to to to to avoid avoid avoid avoid 

Avoid heating. Temperatures above 13°C promote the liquid-vapour phase transition and the formation of 

explosive atmosphere. 

Keep away from sources of ignition. 

Due to the high vapour pressure, containers are liable to burst if temperature rises. 

10. 10.5 10. 

Materials Materials Materials Materials to to to to avoid avoid avoid avoid 

Incompatible materials: various plastics and rubber will be affected. 

Only use solvent resistant instruments. 

10. 10.6 10. 

Hazardous Hazardous Hazardous Hazardous decomposition decomposition decomposition decomposition products products products products 

Reaction with strong oxidising agents, strong reducing agents, acids, acid anhydrides and 

alkali metals under formation of flammable gases (e.g. hydrogen). 

In case of heating, formation of carbon monoxide and formaldehyde is possible. 

For hazardous combustion products see subsection 5.2. 

11. Toxicological Toxicological information 

11.1 11.1 Information Information Information Information on on on on toxicological toxicological toxicological toxicological effects effects effects effects 

11.1 11.1.1 11.1 .1 Toxic Toxicokinetics, Toxic Toxicokinetics, 

okinetics, okinetics, metabolism metabolism metabolism metabolism and and and and distribution 

distribution 

distribution 

distribution 

No data are available for the product. 

11. 11.1. 11. 

1. 1.2 1. Acute Acute Acute Acute effects effects effects effects (acute (acute (acute (acute toxicity, toxicity, toxicity, toxicity, irritation irritation irritation irritation and and and and corrosivity) 

corrosivity) corrosivity) 

corrosivity) 

LD50 rat, oral (mg/kg) 6200 (ethanol) (RTECS) 

28000 (polyethylene glycol 200) (RTECS) 

LD50 rabbit, dermal (mg/kg) > 20000 (polyethylene glycol 200) (RTECS) 

LC50 rat, inhalation (mg/l/4h) 95.6 (ethanol) (RTECS) 

Irritant effect on skin (rabbit) no irritation (ethanol) (OECD Guideline 404) 

Irritant effect on eyes (rabbit) 

11. 11.1. 11. 

1. 1.3 1. Sensitisation 

Sensitisation 

Sensitisation 

Sensitisation 

slight irritation (ethanol) (OECD Guideline 405) 

Sensitisation test (Magnusson and Kligman) negative (ethanol) (IUCLID)


Page 6 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


11. 11.1.4 11. 

1.4 CMR CMR CMR CMR effects effects effects effects (carcinogenic 

(carcinogen 

(carcinogen 

(carcinogenic 

icity, icity, 

ity, ity, mutagenicity, mutagenicity, mutagenicity, mutagenicity, toxicity toxicity toxicity toxicity for for for for the the the the reproduction) 

reproduction) 

reproduction) 

reproduction) 

Carcinogenicity No data available. 

Mutagenicity No data available. 

Toxicity for the reproduction No data available. 

11. 11.1.5 11. 

1.5 Comprehensive Comprehensive Comprehensive Comprehensive evaluation evaluation evaluation evaluation of of of of the the the the CMR CMR CMR CMR properties properties properties properties of of of of substances substances substances substances subject subject subject subject to to to to registration 

registration 

registration 

registration 

No data available. 

11.1.6 11.1.6 Information Information Information Information on on on on likely likely likely likely routes routes routes routes of of of of exposure exposure exposure exposure 

Inhalation: causes a state of intoxication. When inhaled in larger quantities, the solvent vapours cause a narcotic effect. 

Skin contact: prolonged or repeated skin contact may cause removal of natural fat from the skin resulting in 

dermatitis (skin inflammation). 

Eye contact: irritant effect. 

Ingestion: nausea, heartburn, vomiting. 

11.1.7 11.1.7 Symptoms Symptoms Symptoms Symptoms related related related related to to to to the the the the physical, physical, physical, physical, chemical chemical chemical chemical and and and and toxicological toxicological toxicological toxicological characteristics 

characteristics 



After inhalation: headache, dizziness, inebriation, excitation, narcotic effect. 

After ingestion: inebriation, nausea, heartburn, vomiting. 

After contact with eyes: burning. 

11.1.8 11.1.8 Delayed Delayed Delayed Delayed and and and and immediate immediate immediate immediate effects effects effects effects as as as as well well well well as as as as chronic chronic chronic chronic effects effects effects effects from from from from short short short short and and and and long long----term long long term term term exposure exposure exposure exposure 

Prolonged or repeated skin contact may cause removal of natural fat from the skin resulting in dermatitis 

(skin inflammation). 

Chronic consumption of large amounts of ethanol leads to organ damage (especially liver damage) and to damage 

of the nervous system. 

11.1.9 11.1.9 Interactive Interactive Interactive Interactive efects efects efects efects 

No information on interactive effects available for the product. 

11. 11.1.10 11. 

1.10 1.10General General General General remarks remarks remarks remarks 

The product has not been tested. Labelling on the basis of physical properties (flash point). 

12. 12. 12. Ecological information 

12.1 12.1 TTTToxicity oxicity oxicity oxicity 

Aquatic Aquatic Aquatic toxicity toxicity: toxicity 

LC50 (fish) 8140 mg/l/48 h (Leuciscus idus; golden orfe) 

(ethanol) 

(IUCLID) 

> 1000 mg/l/96 h (Cyprinus carpio; carp) 

(polyethylene glycol 200) 

(OECD 203) 

EC50 (daphnia) 9268 - 14221 mg/l/48 h (Daphnia magna) 

(ethanol) 

(IUCLID) 

> 1000 mg/l/48 h (Daphnia magna) 

polyethylene glycol 200) 

(OECD 202) 

IC50 (algae) > 1000 mg/l/ 72 h (Desmodesmus subspicatus) 

(polyethylene glycol 200) 

(OECD 201) 

12. 12.2 12. 

Behaviour in sewage works: 

Treat by state-of-the-art technology before discharging into drains. 

Persistence Persistence Persistence Persistence and and and and degradability 

degradability 

degradability 

degradability 

Ethanol: biodegradation 94% (aqueous solution) (OECD 301 E). Readily biodegradable. 

12. 12.3 12. 

Bioaccumulative Bioaccumulative Bioaccumulative Bioaccumulative potential potential potential potential 

Partition coefficient n-octanol/water: - 0.3 (ethanol) (LOGKOW © databank) 4 

12.4 12.4 

No bioaccumulation is to be expected (log Pow


Page 7 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


13. 3. Disposal Disposal considerations 

considerations 

considerations 

13.1 13.1 Waste Waste Waste Waste treatment treatment treatment treatment methods methods methods methods 

Waste disposal according to official state regulations. Consult the local waste disposal expert about waste disposal. 

Sewage disposal must be avoided. 

Disposal operations/recovery operations accor according accor 

ding to Directive Directive 2008/98/EC 

2008/98/EC 

Disposal operations: D 10 Incineration on land 

R 1 Use principally as a fuel or other means to generate energy 

Recovery operations: R 2 Solvent reclamation/regeneration 

Properties of of waste which which render it hazardous in ac accordance ac 

cordance with with Annex Annex III III of Directive 2008/98/E 2008/98/EC 

2008/98/E 

H 3-B: Flammable 

13.1 13.1.1 13.1 .1 Product Product Product Product / / / / unused unused unused unused product product product product 

Waste disposal corresponding to European Waste Catalogue. Wastes must be classified with respect to their origin 

and depending on different processing steps. The waste codes mentioned as follows are only constituted as our 

recommendations. Referring to the particular case they should be completed or revised. 

EC waste code: 07 07 04 

Waste notation: 

13. 13.1. 13. 1. 1.2 1. Contaminated Contaminated Contaminated Contaminated packaging packaging packaging packaging 

other organic solvents, washing liquids and mother liquors 

Recommendation: Contaminated packaging should be emptied as far as possible and after 

appropriate cleansing may be taken for reuse. 

Recommended cleansing agent: 

Packaging that cannot be cleaned: 

Water. 

EC waste code: 15 01 10 

Waste notation: packaging containing residues of or contaminated by dangerous substances 

14. 14. Transport Transport information 

information 

14.1 14.1 UN UN UN UN number number number number 

UN 1170 

14.2 14.2 UN UN UN UN proper proper proper proper shipping shipping shipping shipping name name name name 

ETHANOL SOLUTION 

14.3 14.3 Transport Transport Transport Transport hazard hazard hazard hazard class(es) class(es) class(es) class(es) 

3 (Flammable liquids) 

14.4 14.4 Packing Packing Packing Packing group group group group 

PG III (Substances presenting low danger) 

14.5 Environmental Environmental Environmental Environmental hazards hazards hazards hazards 

Not relevant. 

14.6 14.6 Special Special Special Special precautions precautions precautions precautions for for for for user user user user 

See Sections 6 to 8. 

14.7 14.7 Transport Transport Transport Transport in in in in bulk bulk bulk bulk according according according according to to to to Annex Annex Annex Annex II II II II of of of of MARPOL MARPOL MARPOL MARPOL 73/78 73/78 73/78 73/78 and and and and the the the the IBC IBC IBC IBC Code Code Code Code 

Not relevant. The transport exclusively takes place in approved and appropriate packaging. 

14.8 14.8 Further Further Further Further information 

information 

information 

information 

ADR: 

ADR: 

Transport category: 3 

Tunnel restriction code according to ADR: (D/E) 

Classification code: 

ADR/RID: 

ADR/RID: 

F1 

Hazard identification number: 

IMDG IMDG-Cod IMDG 

Cod Code: 

e: 

30 

EmS: F-E, S-D 

15. Regulatory information 

15.1 15.1 Safety, Safety, Safety, Safety, health health health health and and and and environmental environmental environmental environmental regulations/legislation regulations/legislation regulations/legislation regulations/legislation specific specific specific specific for for for for the the the the substance substance substance substance or or or or mixture mixture mixture mixture 

15.1.1 15.1.1 Information Information Information Information regarding regarding regarding regarding relevant relevant relevant relevant Community Community Community Community provisions provisions provisions provisions 

- Directive 96/82/EC for danger control following severe accidents with dangerous substances: 

annex I, part 2, category 6. 

- Observe employment restrictions under the law for the protection of young people at work (94/33/EC). 

- Observe Directive 98/24/EC for employee health protection against the threat of chemical substances in the 

workplace. 

- In case of formation of explosive vapour/air mixtures, Directives 94/9/EC and 1999/92/EG must be observed.


Page 8 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


15.1.2 15.1.2 Information Information Information Information regarding regarding regarding regarding national national national national laws/national laws/national 

laws/national 

laws/national measures measures measures measures that that that that may may may may be be be be relevant relevant relevant relevant (for (for (for (for Germany Germany Germany Germany only) only) only) only) 

Restriction of occupation: Youth Employment Protection Act has to be 

observed. 

Major-accident regulation: Annex I No 6 (flammable) 

Fire and explosion hazards: Annex I No 1 and Article 11 German Ordinance on 

Hazardous Substances; 

Operational Safety Regulation Betriebssicherheitsverordnung) 

in accordance with EC-Directive 

1999/92/EC has to be observed 

Regulation on clean air (TA Luft): Number 5.2.5 organic compounds < 30% ethanol 

Water hazard class: WGK 1 – low hazardous to water 

(calculation according to KBwS) 5 

The Federal State Enactment for Facilities to Handle 

Water Endangering Substances (German VAwS– 

Anlagen-Verordnung) has to be observed. 

German Ordinance on Hazardous Substances 

(in accordance with EC-Directive 98/24/EC): 

Regulation on Occupational Medical Prevention 

Articles 6, 7, 8, 9, 11, 14, Annex I No 1 must be 

observed 

(ArbMedVV): Annex, Part 1 (2)c: Activities involving ethanol for 

which workers are to be afforded the opportunity to 

undergo preventive medical check-ups. 

Technical Rules for Hazardous Substances1 : TRGS 400, 402, 420, 500, 510, 555, 720, 721, 722, 

900 

Technical Rules for Industrial Safety1 : TRBS 2152, 2152 Part 1, 2152 Part 2, 2152 Part 3, 

2152 Part 4, 2153 

Rules of the employers´ liability insurance association2 : BGR 104, 189, 190, 192, 195 

Classification in accordance with the easy-to-use workplace control scheme for hazardous substances of the Federal 

Institute for Occupational Safety and Health, version 2.1, 20081 : inhalation: hazard group A 

15. 15.2 15. 

Chemical Chemical Chemical Chemical Safety Safety Safety Safety Assessment 

Assessment 

Assessment 

Assessment 

No Chemical Safety Assessment has been carried out for a substance in the product. 

16. Other information 

16.1 16.1 Keeping Keeping Keeping Keeping (restrictions) (restrictions) 

(restrictions) 

(restrictions) 

Article 8 (5) and (6) German Ordinance on Hazardous Substances 

(for Germany only) 

Supply Supply Supply Supply 

University (college, academy), industry consumer 

16.2 16.2 Full Full Full Full text text text text of of of of the the the the R RR 

R phrases phrases phrases phrases referred referred referred referred to to to to under under under under point point point point 3.2.2 3.2.2 3.2.2 3.2.2 of of of of the the the the Safety Safety Safety Safety Data Data Data Data Sheet Sheet Sheet Sheet 

R11 Highly flammable. 

16.3 16.3 Full Full Full Full text text text text of of of of the the the the hazard hazard hazard hazard statements statements statements statements referred refer refer referred 

red red to to to to under under under under point point point point 3.2.3 3.2.3 3.2.3 3.2.3 of of of of the the the the Safety Safety Safety Safety Data Data Data Data Sheet Sheet Sheet Sheet 

H225 Highly flammable liquid and vapour. 

16.4 16.4 Classification Classification Classification Classification and and and and labelling labelling labelling labelling in in in in accordance accordance accordance accordance with with with with Regulation Regulation Regulation Regulation (EC) (EC) (EC) (EC) No No No No 1272/2008 

1272/2008 

1272/2008 

1272/2008 

16.4.1 16.4.1 Classification 




Flam. Liq. 3; H226 

16.4.2 16.4.2 Labelling Labelling Labelling Labelling 

Hazard pictogram(s): 

Signal word(s): Warning 

Product identifier: AnaRapid Geldrying solution 

Hazard statements: H226 Flammable liquid and vapour. 

Precuationary statements: P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. 

P233 Keep container tightly closed. 

Remark: The classification and labelling of the product in accordance with Regulation (EC) 

No 1272/2008 has been provided with the assistance of the the GHS-converter6 of 

the employers´ liability insurance association.


Page 9 of 9 




4 , DD-64 

D 64 6440 


Gross 



int+49 

(0)61 (0)6162 

62-809840 

62 809840 Revision: 30.04.2011 


16. 6. 6.5 6. Key Key Key Key to to to to abbreviations abbreviations abbreviations abbreviations and and and and acronyms acronyms acronyms acronyms used used used used in in in in the the the the safety safety safety safety data data data data sheet sheet sheet sheet 

ADN: Accord européen relatif au transport international des marchandises dangereuses 

par voie de navigation intérieure 

ADR: Accord européen relatif au transport international des marchandises dangereuses 

par route 

AOX: adsorbable organically bound halogens 

ICAO: International Civil Aviation Organisation. 

IMDG-Code: International Maritime Dangerous Goods-Code 

IUCLID: International Uniform ChemicaL Information Database 

KBwS: Commission for the Evaluation of substances hazardous to waters 

(Kommission Bewertung wassergefährdende Stoffe) 

LGK: Lagerklasse (storage class) 

OECD: Organisation for Economic Co-operation and Development 

PBT: persistent, bioaccumulative and toxic 

RID: Règlement international concernant le transport des marchandises dangereuses 

par chemin de fer 

RTECS : Registry of Toxic Effects of Chemical Substances 

TRBS: Technische Regeln für Betriebssicherheit (Technical Rules for Industrial Safety) 

TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Hazardous Substances) 

vPvB: very persistent and very bioaccumulative 

16. 16.6 16. 

Literature Literature Literature Literature references references references references and and and and sources sources sources sources for for for for data data data data 

1 http://www.baua.de 

2 http://www.arbeitssicherheit.de 

3 http://www.dguv.de/ifa/de/gestis/stoffdb/index.jsp 

4 http://logkow.cisti.nrc.ca 

5 http://www.umweltbundesamt.de 

6 http://www.gischem.de/ghs/index.htm 

16. 16.7 16. 

Method Method Method Method used used used used for for for for the the the the classification classification classification classification of of of of the the the the mixture mixture mixture mixture 

Classification of this mixture on the basis of physical properties (flash point). 

16.8 16.8 Changes Changes Changes Changes which which which which have have have have been been been been made made made made to to to to the the the the previous previous previous previous version version version version of of of of the the the the safety safety safety safety data data data data sheet sheet sheet sheet 

Revised Sections: due to adaptation to Annex I of the Regulation (EU) No 453/2010 (amendment of Annex II 

of Regulation (EC) No 1907/2006), this safety data sheet has been completely revised. 

The The above above information information describes describes exclusively exclusively the the safety safety requirements requirements of of the the product product and and is is based based on on our 

our 

present present-day present 

day day knowledge. The information is intended to give you advice about the the safe hand handling hand 

ling of the product 

named named in in this this safety safety data data sheet, sheet, for for storage, storage, processing, processing, transport transport and and disposal. disposal. The The information information cannot cannot be 

be 

transferred to other products. In the case of mixing the product with other products or in in the case of 

processing, the info information info 

rmation rmation on on this this safety safety data data sheet sheet is is not not necessarily necessarily valid valid for for the the new new made-up made 

up up material. 

material. 

Compiled by: Dr. Dr. Michael Michael Urban Urban 

Urban 

Fachberatung Fachberatung Fachberatung Gefahrstoff Gefahrstoff Gefahrgut 

Gefahrgut 

Vogelbeerweg 3 D-26180 Rastede-Ipwege / Germany 

Tel.: int+49-(0)4402-695620 Fax: int+49-(0)4402-695621

Anarapid gel drying solution - anamed Elektrophorese Gele und ...

Create successful ePaper yourself

Delete template?

Save as template?